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121.
低密度开孔泡沫材料力学模型的理论研究进展 总被引:17,自引:0,他引:17
开孔泡沫材料主要用于隔音、减振和填充方面,对其力学行为进行理论描述,探讨力学性能与密度及复杂微结构的关系具有十分重要的学术价值和工程意义.为了促进国内泡沫材料力学的发展和交流,文中对低密度开孔泡沫材料力学模型的研究历史进行了简要回顾,重点介绍了能较好地反映开孔泡沫材料真实胞体结构特点的十四面体胞体模型和随机胞体模型,并报道了近年来基于十四面体胞体模型和随机胞体模型研究低密度开孔泡沫材料力学行为的一些理论工作、同时,也对国内的一些相关研究情况进行了简要评述,指出了该领域今后的一些研究方向. 相似文献
122.
Simulation of crack spacing using a reinforced concrete model with an internal length parameter 总被引:3,自引:0,他引:3
Summary A gradient-enhanced smeared crack model and bond-slip interface elements are utilized in finite element simulations of reinforced
concrete. The crack model is rooted in an enhanced plasticity theory. It uses the Rankine failure surface dependent on an
equivalent inelastic strain measure as well as on its Laplacian. As a result, finitely sized fracture process zones and realistic
crack spacings are obtained. A reinforced concrete bar in uniaxial tension is analyzed to demonstrate the regularizing influence
of the internal length parameter in the model and to evaluate the influence of the model parameters on the energy dissipation
in multiple cracks. A comparison of numerical simulations with experimental results for a beam without shear reinforcement
in four-point bending concludes the analysis.
Received 4 November 1997; accepted for publication 23 April 1998 相似文献
123.
IntroductionHowtheintensionandmoduleofsteelfibrereinforcedconcrete (SFRC)dependsonitsconstituentpropertiesandcontentisaprincipalproblemtopredictmacro_mechanicspropertiesofSFRC,thekeyconsistsintheconfirmationofstressdistribution .Interfacialstresstransfe… 相似文献
124.
聚氨酯泡沫塑料压缩杨氏模量的理论预测 总被引:6,自引:0,他引:6
通过微分法导出了泡沫塑料剪切模量和体积模量所满足的微分方程组,再利用联系泡沫塑料泊松比和孔隙比的Kerner-Rusch经验关系及泡沫塑料弹性常数间满足足的关系,在基体材料不可压缩的假设下,确定了泡沫塑料的杨氏模量。本文针对几种密度的泡沫塑料,分别对它们的杨氏模量进行了理论预测和实验测定,结果表明:理论预测的模量在较高密度下与实验符合的很好,在低密度下也给出相当好的近似值。此外,本文的结果同其他理 相似文献
125.
Rosaria Ciriminna Dr. Alexandra Fidalgo Prof. Laura M Ilharco Dr. Mario Pagliaro 《ChemistryOpen》2015,4(2):78-126
Porous silica-based microspheres encapsulating aqueous glycerol can be potential curing agents for one-component foams (OCFs). Such agents have the advantage of an enhanced sustainability profile on top of being environmentally friendly materials. A synthetically convenient and scalable sol-gel process was used to make silica and organosilica microspheres doped with aqueous glycerol. These methyl-modified silica microspheres, named “GreenCaps”, exhibit remarkable physical and chemical stability. The microspheres were characterized by scanning electron microscopy, transmission electron microscopy at reduced pressure, and cryogenic nitrogen adsorption—desorption analysis. The structure of the materials was also analyzed at the molecular level by diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy. As expected, the degree of methylation affects the degree of encapsulation and pore structure. Microspheres similarly methylated, however, can differ considerably in surface area and pore size due to the templating effect of glycerol on the organosilica structure. The results of the structure analysis reveal that glycerol is efficiently encapsulated, acts as a template, barely leaches over time, but is released by depressurization. A proper application of these microspheres can later on enhance both the environmental and health profile, as well as the technical performance (curing speed, foam quality, and froth thixotropy) of spray polyurethane foams. 相似文献
126.
Graphene is scientifically and commercially important because of its unique molecular structure which is monoatomic in thickness, rigorously two-dimensional and highly conjugated. Consequently, graphene exhibits exceptional electrical, optical, thermal and mechanical properties. Herein, we critically discuss the surface modification of graphene, the specific advantages that graphene-based materials can provide over other materials in sensor research and their related chemical and electrochemical properties. Furthermore, we describe the latest developments in the use of these materials for sensing technology, including chemical sensors and biosensors and their applications in security, environmental safety and diseases detection and diagnosis. 相似文献
127.
A novel method to prepare microcellular poly(vinyl alcohol) foam based on thermal processing and supercritical fluid 下载免费PDF全文
Combining the thermal processing and supercritical fluid technology develops a novel preparation method of microcellular poly(vinyl alcohol) (PVA). Water, as the plasticizer in system, can form the hydrogen bonding with pendant hydroxyl of PVA and weaken its strong intermolecular and intramolecular forces to realize the thermal processing. Supercritical carbon dioxide (sc‐CO2) can easily dissolve into water‐plasticized PVA (WPVA) because of the destruction of crystal region caused by water, and the enhanced sc‐CO2 solubility can greatly improve the foamability of WPVA. The porous structure generates through the saturation of sc‐CO2 in WPVA sample and followed by pressure drop‐induced phase separation. The foaming behavior of WPVA was studied as a function of saturation pressure, foaming temperature, and saturation time. The cell density, cell size, and distribution of the obtained foam can be controlled by tuning processing conditions. The results revealed that the cell size decreased, and its distribution narrowed with saturation pressure increasing, or decrease of foaming temperature. But excessively increasing the saturation time generated a negative effect on the foaming behavior owing to the deteriorated plasticization effect resulted from the loss of water. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
128.
为了分析及深入探讨混凝土在受拉加载及卸载情况下的力学特性,基于随机损伤本构关系提出了一种混凝土轴拉加卸载模型,推导出了混凝土加卸载的应力 应变关系表达式.为了印证理论表达式,进行了混凝土轴向拉伸及加卸载的试验研究,测得了混凝土的材料参数及其相应的轴拉加卸载应力-应变曲线.结合模型的计算结果,对混凝土的轴拉加卸载试验结果进行了对比分析,结果表明:混凝土轴拉加卸载模型能够预测混凝土的极限强度,同时能描述混凝土的强度软化、加载过程中的弹模折减及卸载后的塑性变形. 相似文献
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